Head to Head
| UEFA Europa League | 2016/02/25 20:05 | Napoli v Villarreal | D | 1-1 |
| UEFA Europa League | 2016/02/18 18:00 | Villarreal v Napoli | L | 1-0 |
Home History
| Italy Serie A | 2022/11/12 14:00 | Napoli v Udinese | W | 3-2 |
| Italy Serie A | 2022/11/08 17:30 | Napoli v Empoli | W | 2-0 |
| Italy Serie A | 2022/11/05 17:00 | Atalanta v Napoli | W | 1-2 |
| UEFA Champions League | 2022/11/01 20:00 | Liverpool v Napoli | L | 2-0 |
| Italy Serie A | 2022/10/29 13:00 | Napoli v Sassuolo | W | 4-0 |
| UEFA Champions League | 2022/10/26 19:00 | Napoli v Rangers | W | 3-0 |
| Italy Serie A | 2022/10/23 18:45 | Roma v Napoli | W | 0-1 |
| Italy Serie A | 2022/10/16 16:00 | Napoli v Bologna | W | 3-2 |
Away History
| Spain Copa del Rey | 2022/11/12 20:00 | Santa Amalia v Villarreal | W | 0-9 |
| Spain La Liga | 2022/11/09 19:00 | Espanyol v Villarreal | W | 0-1 |
| Spain La Liga | 2022/11/06 17:30 | Villarreal v Mallorca | L | 0-2 |
| UEFA Conference League | 2022/11/03 20:00 | Lech Poznan v Villarreal | L | 3-0 |
| Spain La Liga | 2022/10/30 17:30 | Athletic Bilbao v Villarreal | L | 1-0 |
| UEFA Conference League | 2022/10/27 16:45 | Villarreal v Hapoel Beer Sheva | D | 2-2 |
| Spain La Liga | 2022/10/23 16:30 | Villarreal v Almeria | W | 2-1 |
| Spain La Liga | 2022/10/20 19:00 | Barcelona v Villarreal | L | 3-0 |