[3] Villarreal 0-2 Barcelona [1] 2025-10-02 15:15
Stadium: Estadio de la Ceramica Round: 17
Referee: Javier Alberola Rojas Home Manager: Marcelino Away Manager: Hansi Flick
Head to Head
| Spain La Liga | 2025/05/18 17:00 | Barcelona v Villarreal | W | 2-3 |
| Spain La Liga | 2024/09/22 16:30 | Villarreal v Barcelona | L | 1-5 |
| Spain La Liga | 2024/01/27 17:30 | Barcelona v Villarreal | W | 3-5 |
| Spain La Liga | 2023/08/27 15:30 | Villarreal v Barcelona | L | 3-4 |
| Spain La Liga | 2023/02/12 20:00 | Villarreal v Barcelona | L | 0-1 |
| Spain La Liga | 2022/10/20 19:00 | Barcelona v Villarreal | L | 3-0 |
| Spain La Liga | 2022/05/22 20:00 | Barcelona v Villarreal | W | 0-2 |
| Spain La Liga | 2021/11/27 20:00 | Villarreal v Barcelona | L | 1-3 |
Home History
| UEFA Champions League | 2025/10/01 19:00 | Villarreal v Juventus | D | 2-2 |
| Spain La Liga | 2025/09/27 19:00 | Villarreal v Athletic Bilbao | W | 1-0 |
| Spain La Liga | 2025/09/23 19:30 | Sevilla v Villarreal | W | 1-2 |
| Spain La Liga | 2025/09/20 16:30 | Villarreal v Osasuna | W | 2-1 |
| UEFA Champions League | 2025/09/16 19:00 | Tottenham v Villarreal | L | 1-0 |
| Spain La Liga | 2025/09/13 19:00 | Atletico Madrid v Villarreal | L | 2-0 |
| Spain La Liga | 2025/08/31 15:00 | Celta Vigo v Villarreal | D | 1-1 |
| Spain La Liga | 2025/08/24 17:30 | Villarreal v Girona | W | 5-0 |
Away History
| UEFA Champions League | 2025/10/01 19:00 | Barcelona v PSG | L | 1-2 |
| Spain La Liga | 2025/09/28 16:30 | Barcelona v Real Sociedad | W | 2-1 |
| Spain La Liga | 2025/09/25 19:30 | Oviedo v Barcelona | W | 1-3 |
| Spain La Liga | 2025/09/21 19:00 | Barcelona v Getafe | W | 3-0 |
| UEFA Champions League | 2025/09/18 19:00 | Newcastle v Barcelona | W | 1-2 |
| Spain La Liga | 2025/09/14 19:00 | Barcelona v Valencia | W | 6-0 |
| Spain La Liga | 2025/08/31 19:30 | Rayo Vallecano v Barcelona | D | 1-1 |
| Spain La Liga | 2025/08/23 19:30 | Levante v Barcelona | W | 2-3 |