Head to Head
| Netherlands Eredivisie Women | 2025/10/04 12:00 | PSV (W) v FC Twente (W) | W | 1-3 |
| Netherlands Super Cup Women | 2025/08/23 12:00 | FC Twente (W) v PSV (W) | W | 3-2 |
| Netherlands Cup Women | 2025/05/24 14:30 | FC Twente (W) v PSV (W) | D | 2-2 |
| Netherlands Cup Women | 2025/05/10 12:00 | PSV (W) v FC Twente (W) | W | 1-2 |
| Netherlands Eredivisie Women | 2025/02/01 15:30 | PSV (W) v FC Twente (W) | D | 2-2 |
| Netherlands Eredivisie Women | 2024/10/05 14:30 | FC Twente (W) v PSV (W) | D | 0-0 |
| Netherlands Cup Women | 2024/05/24 17:30 | FC Twente (W) v PSV (W) | W | 3-2 |
| Netherlands Eredivisie Women | 2024/03/10 15:45 | FC Twente (W) v PSV (W) | W | 3-1 |
Home History
| UEFA Women's Champions League | 2025/10/08 16:45 | FC Twente (W) v Chelsea (W) | D | 1-1 |
| Netherlands Eredivisie Women | 2025/10/04 12:00 | PSV (W) v FC Twente (W) | W | 1-3 |
| Netherlands Eredivisie Women | 2025/09/28 14:45 | PEC Zwolle (W) v FC Twente (W) | W | 1-4 |
| Netherlands Eredivisie Women | 2025/09/21 14:45 | FC Twente (W) v NAC (W) | W | 6-0 |
| UEFA Women's Champions League Qualifying | 2025/09/18 17:00 | FC Twente (W) v GKS Katowice (W) | W | 4-1 |
| UEFA Women's Champions League Qualifying | 2025/09/11 16:00 | GKS Katowice (W) v FC Twente (W) | W | 0-4 |
| Netherlands Eredivisie Women | 2025/09/06 12:00 | Heerenveen (W) v FC Twente (W) | W | 1-3 |
| UEFA Women's Champions League Qualifying | 2025/08/30 17:00 | FC Twente (W) v Breidablik (W) | W | 2-0 |
Away History
| Netherlands Eredivisie Women | 2025/10/04 12:00 | PSV (W) v FC Twente (W) | L | 1-3 |
| Netherlands Eredivisie Women | 2025/09/28 14:45 | PSV (W) v HERA United (W) | W | 4-0 |
| Netherlands Eredivisie Women | 2025/09/21 14:45 | FC Utrecht (W) v PSV (W) | W | 1-2 |
| UEFA Women's Europa Cup Qualifying | 2025/09/17 17:00 | PSV (W) v Rosenborg (W) | W | 4-0 |
| UEFA Women's Europa Cup Qualifying | 2025/09/10 16:00 | Rosenborg (W) v PSV (W) | L | 3-0 |
| Netherlands Eredivisie Women | 2025/09/06 14:30 | PSV (W) v Excelsior (W) | W | 1-0 |
| UEFA Women's Champions League Qualifying | 2025/08/30 10:00 | Zhitlobud-1 Women v PSV (W) | W | 0-2 |
| UEFA Women's Champions League Qualifying | 2025/08/27 10:00 | Man Utd (W) v PSV (W) | L | 4-0 |