[8] Olympiakos B 2-0 Niki Volou [4] 2021-09-20 20:45
Round: 16
Home Manager: Ariel Miguel Santiago Ibagaza Away Manager: Alekos Vosniadis
Away History
| Europe Friendlies | 2021/09/04 16:00 | Volos NFC v Niki Volou | L | 2-0 |
| Greece Football League | 2021/06/26 14:00 | Episkopi FC v Niki Volou | D | 0-0 |
| Greece Football League | 2021/06/19 14:00 | Athens Kallithea v Niki Volou | D | 0-0 |
| Greece Football League | 2021/06/13 14:00 | Niki Volou v Enosi Panaspropirgiakou Doxa | W | 6-1 |
| Greece Football League | 2021/06/05 14:00 | Niki Volou v Kalamata | D | 2-2 |
| Greece Football League | 2021/05/29 13:00 | AS Santorini v Niki Volou | W | 0-1 |
| Greece Football League | 2021/05/23 14:00 | Niki Volou v Asteras Vlachioti | W | 1-0 |
| Greece Football League | 2021/05/19 14:00 | Enosi Panaspropirgiakou Doxa v Niki Volou | L | 3-2 |