Stadium: Sibur Arena Round: 27 Ground: Hardcourt outdoor
| WTA Linz WD | 2021/11/10 18:00 | Wang/Zheng v Alexandrova/Sizikova | 6-3,6-3 |
| WTA Linz WD | 2021/11/09 15:20 | Alexandrova/Sizikova v Rosolska/Routliffe | 4-6,6-1,12-10 |
| WTA Moscow WD | 2021/10/21 13:30 | Alexandrova/Sizikova v Dzalamidze/Rakhimova | 1-6,6-4,7-10 |
| WTA Moscow WD | 2021/10/20 16:55 | Guarachi/Krawczyk v Alexandrova/Sizikova | 3-6,1-6 |
| French Open Women WD | 2021/06/03 14:30 | Sanders/Tomljanovic v Alexandrova/Sizikova | 6-1,6-1 |
| WTA Strasbourg WD | 2021/05/24 12:15 | Alexandrova/Sizikova v Ninomiya/Yang | 4-6,4-6 |
| WTA St. Petersburg WD | 2021/03/16 16:55 | Rodionova/Van Der Hoek v Alexandrova/Sizikova | 6-2,6-2 |
| WTA Lyon WD | 2021/03/03 14:25 | Alexandrova/Sizikova v Danilina/Marozava | 1-6,4-6 |
| WTA Karlsruhe WD | 2021/09/10 11:00 | Dzalamidze/Panova v Bara/Gorgodze | 3-6,1-6 |
| WTA Karlsruhe WD | 2021/09/07 12:20 | Sharma/Van Der Hoek v Dzalamidze/Panova | 1-6,4-6 |