[8] Villarreal 0-1 Barcelona [1] 2023-01-12 14:00
Stadium: Estadio de la Ceramica Round: 21
Referee: Alejandro Jose Hernandez Hernandez Home Manager: Quique Setien Away Manager: Xavi
Head to Head
| Spain La Liga | 2022/10/20 19:00 | Barcelona v Villarreal | L | 3-0 |
| Spain La Liga | 2022/05/22 20:00 | Barcelona v Villarreal | W | 0-2 |
| Spain La Liga | 2021/11/27 20:00 | Villarreal v Barcelona | L | 1-3 |
| Spain La Liga | 2021/04/25 14:15 | Villarreal v Barcelona | L | 1-2 |
| Spain La Liga | 2020/09/27 19:00 | Barcelona v Villarreal | L | 4-0 |
| Spain La Liga | 2020/07/05 20:00 | Villarreal v Barcelona | L | 1-4 |
| Spain La Liga | 2019/09/24 19:00 | Barcelona v Villarreal | L | 2-1 |
| Spain La Liga | 2019/04/02 19:30 | Villarreal v Barcelona | D | 4-4 |
Home History
| Spain La Liga | 2023/01/07 15:15 | Villarreal v Real Madrid | W | 2-1 |
| Spain Copa del Rey | 2023/01/03 18:00 | FC Cartagena v Villarreal | W | 1-5 |
| Spain La Liga | 2022/12/31 15:15 | Villarreal v Valencia | W | 2-1 |
| Spain Copa del Rey | 2022/12/20 20:00 | Guijuelo v Villarreal | D | 1-1 |
| Elite Club Friendlies | 2022/12/17 19:30 | Napoli v Villarreal | W | 2-3 |
| Elite Club Friendlies | 2022/12/15 20:00 | Aston Villa v Villarreal | W | 0-1 |
| Europe Friendlies | 2022/12/06 17:00 | Galatasaray v Villarreal | W | 3-4 |
| Europe Friendlies | 2022/12/03 16:00 | Fenerbahce v Villarreal | L | 2-1 |
Away History
| Spain La Liga | 2023/01/08 20:00 | Atletico Madrid v Barcelona | W | 0-1 |
| Spain Copa del Rey | 2023/01/04 20:00 | CF Intercity v Barcelona | D | 3-3 |
| Spain La Liga | 2022/12/31 13:00 | Barcelona v Espanyol | D | 1-1 |
| Spain La Liga | 2022/11/08 20:30 | Osasuna v Barcelona | W | 1-2 |
| Spain La Liga | 2022/11/05 20:00 | Barcelona v Almeria | W | 2-0 |
| UEFA Champions League | 2022/11/01 20:00 | Viktoria Plzen v Barcelona | W | 2-4 |
| Spain La Liga | 2022/10/29 19:00 | Valencia v Barcelona | W | 0-1 |
| UEFA Champions League | 2022/10/26 19:00 | Barcelona v Bayern Munich | L | 0-3 |