[8] Villarreal 0-1 Baker/Mektic [1] 2022-10-02 02:00
Stadium: Estadio de la Ceramica Round: 21
Referee: Alejandro Jose Hernandez Hernandez Home Manager: Quique Setien Away Manager: Xavi
Head to Head
| Spain La Liga | 2022/05/22 20:00 | Barcelona v Villarreal | W | 0-2 |
| Spain La Liga | 2021/11/27 20:00 | Villarreal v Barcelona | L | 1-3 |
| Spain La Liga | 2021/04/25 14:15 | Villarreal v Barcelona | L | 1-2 |
| Spain La Liga | 2020/09/27 19:00 | Barcelona v Villarreal | L | 4-0 |
| Spain La Liga | 2020/07/05 20:00 | Villarreal v Barcelona | L | 1-4 |
| Spain La Liga | 2019/09/24 19:00 | Barcelona v Villarreal | L | 2-1 |
| Spain La Liga | 2019/04/02 19:30 | Villarreal v Barcelona | D | 4-4 |
| Spain La Liga | 2018/12/02 17:30 | Barcelona v Villarreal | L | 2-0 |
Home History
| Spain La Liga | 2022/10/01 12:00 | Cadiz v Villarreal | D | 0-0 |
| Spain La Liga | 2022/09/18 14:15 | Villarreal v Sevilla | D | 1-1 |
| UEFA Conference League | 2022/09/15 19:00 | Hapoel Beer Sheva v Villarreal | W | 1-2 |
| Spain La Liga | 2022/09/11 19:00 | Real Betis v Villarreal | L | 1-0 |
| UEFA Conference League | 2022/09/08 16:45 | Villarreal v Lech Poznan | W | 4-3 |
| Spain La Liga | 2022/09/04 16:30 | Villarreal v Elche | W | 4-0 |
| Spain La Liga | 2022/08/28 15:30 | Getafe v Villarreal | D | 0-0 |
| UEFA Conference League Qualifying | 2022/08/25 19:00 | Hajduk Split v Villarreal | W | 0-2 |
Away History
| Spain La Liga | 2022/10/01 19:00 | Mallorca v Barcelona | W | 0-1 |
| Spain La Liga | 2022/09/17 14:15 | Barcelona v Elche | W | 3-0 |
| UEFA Champions League | 2022/09/13 19:00 | Bayern Munich v Barcelona | L | 2-0 |
| Spain La Liga | 2022/09/10 16:30 | Cadiz v Barcelona | W | 0-4 |
| UEFA Champions League | 2022/09/07 19:00 | Barcelona v Viktoria Plzen | W | 5-1 |
| Spain La Liga | 2022/09/03 19:00 | Sevilla v Barcelona | W | 0-3 |
| Spain La Liga | 2022/08/28 17:30 | Barcelona v Valladolid | W | 4-0 |
| Elite Club Friendlies | 2022/08/24 19:30 | Barcelona v Man City | D | 3-3 |