Stadium: Grandstand Round: 27 Ground: Hardcourt outdoor
| French Open Women WD | 2023/06/05 11:25 | Hunter/Mertens v Kudermetova/Samsonova | 3-6,4-6 |
| French Open Women WD | 2023/06/03 09:00 | Hunter/Mertens v Martins/Shymanovich | 7-6,6-1 |
| French Open Women WD | 2023/06/02 13:30 | Hunter/Mertens v Collins/Navarro | 6-2,6-2 |
| WTA Rome WD | 2023/05/20 19:20 | Gauff/Pegula v Hunter/Mertens | 4-6,4-6 |
| WTA Rome WD | 2023/05/18 17:00 | Hunter/Mertens v Bouzkova/Mattek-Sands | 7-5,6-4 |
| WTA Rome WD | 2023/05/15 14:30 | Babos/Danilina v Hunter/Mertens | 4-6,2-6 |
| WTA Rome WD | 2023/05/14 10:00 | Moratelli/Rosatello v Hunter/Mertens | 1-6,6-7 |
| WTA Rome WD | 2023/05/11 18:15 | Flipkens/Rosolska v Hunter/Mertens | 0-6,7-6,4-10 |