Head to Head
| WTA Auckland | 2025/01/01 05:55 | Katie Volynets v Ann Li | 6-4,6-3 |
| WTA Charleston | 2024/03/31 19:35 | Katie Volynets v Ann Li | 2-6,6-1,6-2 |
Home History
| WTA Hobart | 2025/01/08 02:15 | Dayana Yastremska v Ann Li | 1-6,7-5,6-2 |
| WTA Hobart | 2025/01/07 00:00 | Sloane Stephens v Ann Li | 5-7,1-6 |
| WTA Hobart | 2025/01/05 00:00 | Suzan Lamens v Ann Li | 1-6,4-6 |
| WTA Hobart | 2025/01/04 02:00 | Chloe Paquet v Ann Li | 6-2,3-6,1-6 |
| WTA Auckland | 2025/01/01 05:55 | Katie Volynets v Ann Li | 6-4,6-3 |
| WTA Auckland | 2024/12/30 05:30 | Ann Li v Sloane Stephens | 5-7,6-4,6-4 |
| WTA Midland | 2024/11/06 19:00 | Ann Li v Astra Sharma | 4-6,6-4,6-7 |
| WTA Merida | 2024/11/04 00:00 | Zeynep Sonmez v Ann Li | 6-2,6-1 |
Away History
| WTA Hobart | 2025/01/07 01:00 | Dayana Yastremska v Katie Volynets | 2-6,6-4,6-1 |
| WTA Auckland | 2025/01/03 23:15 | Katie Volynets v Alycia Parks | 1-6,4-6 |
| WTA Auckland | 2025/01/01 05:55 | Katie Volynets v Ann Li | 6-4,6-3 |
| WTA Auckland | 2024/12/30 08:05 | Katie Volynets v Erika Andreeva | 6-4,6-7,6-2 |
| WTA Osaka | 2024/10/14 01:30 | Clara Tauson v Katie Volynets | 6-1,6-4 |
| WTA Wuhan | 2024/10/07 03:00 | Anastasia Potapova v Katie Volynets | 5-7,6-3,7-5 |
| WTA Beijing | 2024/09/30 04:00 | Katie Volynets v Naomi Osaka | 3-6,2-6 |
| WTA Beijing | 2024/09/27 08:50 | Marta Kostyuk v Katie Volynets | 5-7,3-6 |